TANDEM CYCLOPROPYLCARBINYL OXIRANYLCARBINYL RADICAL REARRANGEMENTS - AN ENTRY INTO THE PROSTAGLANDIN B-1 SERIES

Authors
ZIEGLER FE PETERSEN AK
Citation
Fe. Ziegler et Ak. Petersen, TANDEM CYCLOPROPYLCARBINYL OXIRANYLCARBINYL RADICAL REARRANGEMENTS - AN ENTRY INTO THE PROSTAGLANDIN B-1 SERIES, Tetrahedron letters, 37(6), 1996, pp. 809-812
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
6
Year of publication
1996
Pages
809 - 812
Database
ISI
SICI code
0040-4039(1996)37:6<809:TCORR->2.0.ZU;2-2
Abstract
A tandem radical fragmentation of a cyclopropylcarbinyl/oxiranylcarbin yl system leads to the PGB(1) series of prostaglandins. Control of cyc lopropane bond fragmentation as a function of C-2 substitution in bicy clo[3.1.0]hexanylcarbinyl radicals is presented.