COMPETITIVE OXIDATION OF 1-PROPANOL AND 2-PROPANOL CATALYZED BY TITANIUM SILICALITE-1 AND THE APPLICATION FOR SELECTIVE OXIDATION OF 1-METHOXY-2-PROPANOL TO 1-METHOXY-2-PROPANONE

Authors
HAYASHI H KIKAWA K MURAI Y SHIGEMOTO N SUGIYAMA S KAWASHIORO K
Citation
H. Hayashi et al., COMPETITIVE OXIDATION OF 1-PROPANOL AND 2-PROPANOL CATALYZED BY TITANIUM SILICALITE-1 AND THE APPLICATION FOR SELECTIVE OXIDATION OF 1-METHOXY-2-PROPANOL TO 1-METHOXY-2-PROPANONE, Catalysis letters, 36(1-2), 1996, pp. 99-102
Citations number
12
Categorie Soggetti
Chemistry Physical
Journal title
Catalysis letters → ACNP
ISSN journal
1011372X
Volume
36
Issue
1-2
Year of publication
1996
Pages
99 - 102
Database
ISI
SICI code
1011-372X(1996)36:1-2<99:COO1A2>2.0.ZU;2-R
Abstract
Oxidation of 2-propanol with hydrogen peroxide catalyzed by TS-1 was s trongly retarded in the presence of an equimolar 1-propanol to a level of 1-propanol oxidation, and the competitive oxidation behavior was a pplied for the selective oxidation of 1-methoxy-2-propanol to afford 1 -methoxy-2-propanone in a high yield of 85%.