ELECTROSYNTHESIS OF THE CYANAMIDE CYCLIC-DERIVATIVES

Authors
PETROSYAN VA IGNATUSHCHENKO LI
Citation
Va. Petrosyan et Li. Ignatushchenko, ELECTROSYNTHESIS OF THE CYANAMIDE CYCLIC-DERIVATIVES, Russian journal of electrochemistry, 32(1), 1996, pp. 117-119
Citations number
10
Categorie Soggetti
Electrochemistry
Journal title
Russian journal of electrochemistry → ACNP
ISSN journal
10231935
Volume
32
Issue
1
Year of publication
1996
Pages
117 - 119
Database
ISI
SICI code
1023-1935(1996)32:1<117:EOTCC>2.0.ZU;2-G
Abstract
The cathodic, galvanostatic, diaphragm electrolysis of cyanamide in ab solute CH3CN, with 0.1 N Bu(4)NClO(4) as a background electrolyte, in the presence of alpha,beta(omega)-dibromoalkanes, was shown to result in the formation of the cyanamide cyclic derivatives. The target proce ss proceeds via a stage of cathodic generation of N-centered anions, w hich then enter the nucleophilic substitution reactions.