A new fructan series, in addition to inulin, was identified in tissue
extracts of Cichorium intybus L., Helianthus tuberosus L. and Taraxacu
m officinale Weber. The second fructan series was separated from the i
nulin series up to degree of polymerization (DP) 18 by ion chromatogra
phy. The DP 4 of this new fructan series was purified and structurally
analysed. Hydrolysis and methylation analysis of the DP 4 oligomer sh
ows that this is a fructan series that contains only beta-2,1-linked f
ructose molecules. We conclude that this new fructan series in species
of Asteraceae comprises the inulo-n-ose series and probably consists
of products of inulin hydrolysis that are formed during inulin mobiliz
ation.