OXIDATION OF TETRAMETHYLTHIURAM SULFIDE AND IRON(III) DITHIOCARBAMATES WITH FERRIC-CHLORIDE

Authors
VICTORIANO LI GNECCO JA CARBACHO HV
Citation
Li. Victoriano et al., OXIDATION OF TETRAMETHYLTHIURAM SULFIDE AND IRON(III) DITHIOCARBAMATES WITH FERRIC-CHLORIDE, Polyhedron, 15(8), 1996, pp. 1315-1321
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
8
Year of publication
1996
Pages
1315 - 1321
Database
ISI
SICI code
0277-5387(1996)15:8<1315:OOTSAI>2.0.ZU;2-P
Abstract
The title systems lead to the haloferrate(III) salt of the large 3,5-b is(N,N-dimethyliminium)-1,2,4-trithiolane cation. Oxidation of the iro n(III) dithiocarbamates occurs stepwise through the formation of sever al intermediates, which are isolated and characterized. An alternative route to the oxidation of the thiuram sulfide is presented. All compo unds were characterized by analyses, IR and UV spectroscopy, as well a s magnetic measurements.