Recent developments in sensor technology show the suitability of thin
pyroelectric films for the construction of pyroelectric sensor devices
made from polymer materials. These materials are used for its advanta
geous thermal properties and also for its suitable frequency behaviour
. Pyroelectrical measurements have been provided on thin films based u
pon poly(vinyl alcohol)s and poly(siloxane)s with azobenzene side chai
ns. Relaxation behaviour and stability of poled pyroelectric polymers
are discussed and related to the results of dipole relaxation measurem
ents provided at our laboratories.