SAND CATALYZED OXIDATIVE CLEAVAGE OF DOUBLE-BONDS

Authors
HUANG BN GUPTON JT HANSEN KC IDOUX JP
Citation
Bn. Huang et al., SAND CATALYZED OXIDATIVE CLEAVAGE OF DOUBLE-BONDS, Synthetic communications, 26(1), 1996, pp. 165-178
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
26
Issue
1
Year of publication
1996
Pages
165 - 178
Database
ISI
SICI code
0039-7911(1996)26:1<165:SCOCOD>2.0.ZU;2-I
Abstract
The discovery of a catalytic effect of sand on the activity of KMnO4/N aIO4 or KMnO4/NaClO oxidant system provides a convenient method for do uble bond cleavage under mild conditions. An oxidative rearrangement o f alpha-bromostyrene to 2-bromoacetophenone was also observed.