Studies on the entrainment swelling of emulsion during batch extractio
n of lactic acid using a liquid surfactant membrane (LSM) system are r
eported. The concept of effective concentration of surfactant in membr
ane phase has been proposed, considering the high adsorption density o
f the surfactant at the droplet interfaces in the LSM system. The swel
ling caused by emulsification during the initial dispersion process wa
s investigated. The swelling ratio was measured by a density method. A
model for estimating the ''emulsification'' swelling ratio, F-se, has
been proposed, based on a mechanism of swelling due to the entrainmen
t of water resulting from the interfacial turbulence and emulsificatio
n in the initial dispersion process.