INTRAMOLECULAR COORDINATION OF THE DIMETHYLAMINO GROUP IN A RHODIUM-OXALATE COMPLEX WITH THE YLAMINO)ETHYL]-2,3,4,5-TETRAMETHYLCYCLOPENTADIENYL LIGAND

Authors
STAMMLER HG JUTZI P NEUMANN B KRISTEN MO HOLSCHER H
Citation
Hg. Stammler et al., INTRAMOLECULAR COORDINATION OF THE DIMETHYLAMINO GROUP IN A RHODIUM-OXALATE COMPLEX WITH THE YLAMINO)ETHYL]-2,3,4,5-TETRAMETHYLCYCLOPENTADIENYL LIGAND, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 2494-2496
Citations number
8
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
12
Pages
2494 - 2496
Database
ISI
SICI code
0108-2701(1995)51:<2494:ICOTDG>2.0.ZU;2-K
Abstract
The title compound, {eta(5)-1-[2-(dimethylamino-kappa lcyclopentadieny l}(oxalato-kappa(2)O,O'')-rhodium, [Rh(C2O4)(C13H22N)], is the first r hodium-oxalate complex incorporating a cyclopentadienyl ligand. In thi s complex, the dimethylamino group of the hemilabile ylamino)ethyl]-2, 3,4,5-tetramethylcyclopentadienyl ligand is coordinated to the Rh atom in an intramolecular manner.