TRICYCLO[8.2.1.0(2,9)]TRIDECA-5,11-DIEN-3-OL

Citation
Fm. Bohnen et al., TRICYCLO[8.2.1.0(2,9)]TRIDECA-5,11-DIEN-3-OL, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 2639-2641
Citations number
15
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
12
Pages
2639 - 2641
Database
ISI
SICI code
0108-2701(1995)51:<2639:T>2.0.ZU;2-O
Abstract
The cylooctenyl fragment of the title compound, C13H18O, adopts a twis t-boat conformation. The torsion angle at the ring-fusion bond is 7.0( 2)degrees and that at the cyclooctene double bond is 0.0(2)degrees. Th e cyclooctenyl C=C bond length is 1.325(3)Angstrom and the norbornenyl C=C bond length is 1.323(2)Angstrom. In accord with the space-group s ymmetry, four molecules are held together by hydrogen bonding, with an intermolecular O ... O distance of 2.736 (1)Angstrom.