A MOLYBDENUM METALLORGANIC COMPLEX - AN XPS INVESTIGATION TO CONFIRM ITS IDENTITY

Authors
BIANCHI CL PORTA F
Citation
Cl. Bianchi et F. Porta, A MOLYBDENUM METALLORGANIC COMPLEX - AN XPS INVESTIGATION TO CONFIRM ITS IDENTITY, Vacuum, 47(2), 1996, pp. 179-182
Citations number
11
Categorie Soggetti
Physics, Applied
Journal title
Vacuum → ACNP
ISSN journal
0042207X
Volume
47
Issue
2
Year of publication
1996
Pages
179 - 182
Database
ISI
SICI code
0042-207X(1996)47:2<179:AMMC-A>2.0.ZU;2-L
Abstract
The oxo-diperoxo complex of molybdenum (VI), Mo(O)(O-2)(2)(HMPA) a, (H 2O) reacts with ClC6H4CH2NH2 to give the cis-dioxoperoxo complex Mo(O) (2)(O-2)(ClC6H4CH2NH2)(2) b. The amorphous complex b has been fully ch aracterized by elemental and thermogravimetric analyses, IR, Raman spe ctroscopy, conductivity, EPR and NMR measurements, and XPS analyses. T he results lead to the conclusion that the compound b is an octahedral complex of molybdenum (VI) bearings two ore-oxygens, a side-on peroxo ligand and two cis-amine ligands.