SYNTHESIS AND CHEMICAL-TRANSFORMATIONS OF THE DIELS-ALDER ADDUCT OF [60]FULLERENE AND 4-AMINO-O-QUINODIMETHANE

Authors
WALTER M GUGEL A SPICKERMANN J BELIK P KRAUS A MULLEN K
Citation
M. Walter et al., SYNTHESIS AND CHEMICAL-TRANSFORMATIONS OF THE DIELS-ALDER ADDUCT OF [60]FULLERENE AND 4-AMINO-O-QUINODIMETHANE, Fullerene science and technology, 4(1), 1996, pp. 101-113
Citations number
24
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical","Material Science
Journal title
Fullerene science and technology → ACNP
ISSN journal
1064122X
Volume
4
Issue
1
Year of publication
1996
Pages
101 - 113
Database
ISI
SICI code
1064-122X(1996)4:1<101:SACOTD>2.0.ZU;2-5
Abstract
Diels-Alder reaction of 4-amino-o-quinodimethane (6) with [60]fulleren e (1) affords the thermally stable and chemically reactive adduct 7(n) . The nucleophilic amino group of 7(n) is well suited for the covalent attachment of different molecules to the [60]fullerene core by furthe r chemical reactions.