DEPROTECTION AND DIRECT OXIDATIVE DEPROTECTION OF TRIMETHYLSILYL ETHERS TO THEIR CORRESPONDING ALCOHOLS AND CARBONYL-COMPOUNDS WITH TRIS[TRINITRATOCERIUM(IV)] PARAPERIODATE, [(NO3)(3)CE](3).H2IO6, IN AN APROTIC-SOLVENT

Authors
FIROUZABADI H SHIRINY F
Citation
H. Firouzabadi et F. Shiriny, DEPROTECTION AND DIRECT OXIDATIVE DEPROTECTION OF TRIMETHYLSILYL ETHERS TO THEIR CORRESPONDING ALCOHOLS AND CARBONYL-COMPOUNDS WITH TRIS[TRINITRATOCERIUM(IV)] PARAPERIODATE, [(NO3)(3)CE](3).H2IO6, IN AN APROTIC-SOLVENT, Synthetic communications, 26(3), 1996, pp. 423-432
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
26
Issue
3
Year of publication
1996
Pages
423 - 432
Database
ISI
SICI code
0039-7911(1996)26:3<423:DADODO>2.0.ZU;2-1
Abstract
Deprotection of structurally different trimethylsilyl ethers to their corresponding alcohols has been achieved in refluxing benzene in the p resence of tris[trinitratocerium(IV)] paraperiodte in a few minutes. T his reagent has also been used successfuly for the direct oxidation of trimethylsilyl ethers to their corresponding carbonyl compounds. Benz ylic double bonds are prone to cleavage reactions with this method.