STRUCTURE AND REACTIVITY OF FRAMEWORK AND EXTRAFRAMEWORK IRON IN FE-SILICALITE AS INVESTIGATED BY SPECTROSCOPIC AND PHYSICOCHEMICAL METHODS

Authors
BORDIGA S BUZZONI R GEOBALDO F LAMBERTI C GIAMELLO E ZECCHINA A LEOFANTI G PETRINI G TOZZOLA G VLAIC G
Citation
S. Bordiga et al., STRUCTURE AND REACTIVITY OF FRAMEWORK AND EXTRAFRAMEWORK IRON IN FE-SILICALITE AS INVESTIGATED BY SPECTROSCOPIC AND PHYSICOCHEMICAL METHODS, Journal of catalysis, 158(2), 1996, pp. 486-501
Citations number
66
Categorie Soggetti
Chemistry Physical
Journal title
Journal of catalysis → ACNP
ISSN journal
00219517
Volume
158
Issue
2
Year of publication
1996
Pages
486 - 501
Database
ISI
SICI code
0021-9517(1996)158:2<486:SAROFA>2.0.ZU;2-3
Abstract
The application of LR, Raman, UV-visible, EPR, XANES, EXAFS, and TPR t echniques to the determination of the Fe3+ local environment in Fe-sil icalite is described and discussed. These methods give information con cerning the structural changes of the zeolitic structure, upon thermal treatments and interaction with adsorbates. In particular the effect of template burning at 773 K or at 973 K on the local Fe3+ environment has been discussed in detail. The reactivity of the zeolite towards N H3 has also been considered. (C) 1996 Academic Press, Inc.