ALLYLATION OF BETA-KETOALDEHYDES AND FUNCTIONALIZED IMINES BY DIALLYLTIN DIBROMIDE - FORMATION OF SKIPPED AND CONJUGATED DIENES

Authors
KUMARASWAMY S NAGABRAHMANANDACHARI S SWAMY KCK
Citation
S. Kumaraswamy et al., ALLYLATION OF BETA-KETOALDEHYDES AND FUNCTIONALIZED IMINES BY DIALLYLTIN DIBROMIDE - FORMATION OF SKIPPED AND CONJUGATED DIENES, Synthetic communications, 26(4), 1996, pp. 729-744
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
26
Issue
4
Year of publication
1996
Pages
729 - 744
Database
ISI
SICI code
0039-7911(1996)26:4<729:AOBAFI>2.0.ZU;2-C
Abstract
Diallyltin dibromide reacts with beta-ketoaldehydes possessing no arom atic side groups and with (hydroxy) aryl imines to afford the expected homoallyl alcohols or amines respectively. With beta-ketoaldehydes ha ving aromatic side groups, skipped or conjugated dienes are obtained d epending on whether or not an aqueous work up procedure is used.