IS(1-PHENYLIMINOETHYL)PYRIDINE-N,N',N'']COPPER(II) DIPERCHLORATE

Authors
BLAKE AJ LAVERY AJ SCHRODER M
Citation
Aj. Blake et al., IS(1-PHENYLIMINOETHYL)PYRIDINE-N,N',N'']COPPER(II) DIPERCHLORATE, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 37-39
Citations number
4
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
1
Pages
37 - 39
Database
ISI
SICI code
0108-2701(1996)52:<37:ID>2.0.ZU;2-P
Abstract
In [Cu(C21H19N3)(2)](ClO4)(2), two tridentate N-donor ligands coordina te to a copper(II) centre to give a distorted octahedral environment. The two ligands are approximately orthogonal, with an angle of 89.7 (2 )degrees between the two CuN3 planes. One of the ligands lies further from the Cu atom, its Cu-N-imino distances (mean 2.31 Angstrom) being 0.21 Angstrom longer than the corresponding distances for the second l igand, an effect which is due to Jahn-Teller distortion.