CIS-(BENZENETHIOLATO)BIS(TERT-BUTYL OCYANIDE)CARBONYL(CYCLOPENTADIENYL)MOLYBDENUM(II), [MO(C6H5S)(C5H9N)(2)-(C5H5)(CO)]

Authors
MCDERMOTT LC MUIR KW PETILLON FY PODERGUILLOU S SCHOLLHAMMER P
Citation
Lc. Mcdermott et al., CIS-(BENZENETHIOLATO)BIS(TERT-BUTYL OCYANIDE)CARBONYL(CYCLOPENTADIENYL)MOLYBDENUM(II), [MO(C6H5S)(C5H9N)(2)-(C5H5)(CO)], Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 74-77
Citations number
10
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
1
Pages
74 - 77
Database
ISI
SICI code
0108-2701(1996)52:<74:CO>2.0.ZU;2-Q
Abstract
In [CpMo(SPh)(CO)(CN(t)Bu)(2)], Cp = eta(5)-C5H5, the Mo atom adopts c onventional four-legged piano-stool coordination geometry; a pair of c is CN(t)Bu ligands, together with carbonyl and benzenthiolato groups, make up the base. The Mo-CN(t)Bu bond lengths [2.053 (4) Angstrom tran s to S, 2.086 (4) Angstrom trans to CO] show a small but significant d ifference.