THERMAL-DECOMPOSITION OF ALLYLIC SULFINIC ACIDS - CONFIRMATION OF A RETRO-ENE MECHANISM

Authors
KING MD SUE RE WHITE RH YOUNG DJ
Citation
Md. King et al., THERMAL-DECOMPOSITION OF ALLYLIC SULFINIC ACIDS - CONFIRMATION OF A RETRO-ENE MECHANISM, Journal of the Chemical Society, Chemical Communications, (24), 1993, pp. 1797-1798
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
24
Year of publication
1993
Pages
1797 - 1798
Database
ISI
SICI code
0022-4936(1993):24<1797:TOASA->2.0.ZU;2-9
Abstract
The acidolysis of trialkyltin allylic sulfinates yields the correspond ing sulfinic acids which undergo a first-order thermal decomposition w ith gamma-syn substitution as predicted for a retro-ene mechanism.