PREPARATIVE-SCALE ORGANOMETALLIC CHEMISTRY IN SUPERCRITICAL FLUIDS - ISOLATION OF [CR(CO)5(C2H4)] AS A STABLE SOLID AT ROOM-TEMPERATURE

Authors
BANISTER JA HOWDLE SM POLIAKOFF M
Citation
Ja. Banister et al., PREPARATIVE-SCALE ORGANOMETALLIC CHEMISTRY IN SUPERCRITICAL FLUIDS - ISOLATION OF [CR(CO)5(C2H4)] AS A STABLE SOLID AT ROOM-TEMPERATURE, Journal of the Chemical Society, Chemical Communications, (24), 1993, pp. 1814-1815
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
24
Year of publication
1993
Pages
1814 - 1815
Database
ISI
SICI code
0022-4936(1993):24<1814:POCISF>2.0.ZU;2-1
Abstract
A miniature flow reactor has been developed for photochemical reaction s in supercritical fluids; [Cr(CO)5(C2H4)] is isolated, for the first time, by the UV photolysis of [Cr(CO)6] in supercritical C2H4 at room temp. with a yield of ca. 40 mg per hour at ca. 80% purity as estimate d by IR spectroscopy.