RECEPTORS FOR THE HYDRAZINIUM ION - SIMULTANEOUS 1ST-SPHERE AND 2ND-SPHERE COORDINATION INSIDE ORGANOPALLADIUM CROWN-ETHER COMPLEXES

Authors
KICKHAM JE LOEB SJ
Citation
Je. Kickham et Sj. Loeb, RECEPTORS FOR THE HYDRAZINIUM ION - SIMULTANEOUS 1ST-SPHERE AND 2ND-SPHERE COORDINATION INSIDE ORGANOPALLADIUM CROWN-ETHER COMPLEXES, Journal of the Chemical Society, Chemical Communications, (24), 1993, pp. 1848-1850
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
24
Year of publication
1993
Pages
1848 - 1850
Database
ISI
SICI code
0022-4936(1993):24<1848:RFTHI->2.0.ZU;2-K
Abstract
Organopalladium crown ether complexes are employed to bind the hydrazi nium ion, [NH2NH3]+, via simultaneous first- and second-sphere coordin ation featuring sigma-donation to Pd and hydrogen bonding to aliphatic ether oxygen atoms.