SYNTHESIS OF MONCATIONIC AND DICATIONIC PHOSPHORUS ZIRCONIUM SPECIES

Authors
BOUTONNET F ZABLOCKA M IGAU A MAJORAL JP RAYNAUD B JAUD J
Citation
F. Boutonnet et al., SYNTHESIS OF MONCATIONIC AND DICATIONIC PHOSPHORUS ZIRCONIUM SPECIES, Journal of the Chemical Society, Chemical Communications, (24), 1993, pp. 1866-1867
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
24
Year of publication
1993
Pages
1866 - 1867
Database
ISI
SICI code
0022-4936(1993):24<1866:SOMADP>2.0.ZU;2-H
Abstract
Synthesis and characterisation of zirconium containing phosphonium sal ts are reported, including the X-ray molecular structure determination of 2P(Me)(CH2)2C(=NBut)Zr(eta-C5H5)2OSO2CF3][OSO2CF3] 5a; lability of the zirconium-oxygen covalent bond in 5a allows the preparation of th e phosphorus-zirconium dicationic species 6a 2)N)2P(Me)(CH2)2C(=NBut)Z r(eta-C5H5)][(OSO2CF3)]2.