SPECTROELECTROCHEMICAL CHARACTERIZATION OF A PYRAZINE-BRIDGED MIXED-VALENT (4D5 4D6) ORGANOMETALLIC ANALOG OF THE CREUTZ-TAUBE ION/

Authors
BRUNS W KAIM W WALDHOR E KREJCIK M
Citation
W. Bruns et al., SPECTROELECTROCHEMICAL CHARACTERIZATION OF A PYRAZINE-BRIDGED MIXED-VALENT (4D5 4D6) ORGANOMETALLIC ANALOG OF THE CREUTZ-TAUBE ION/, Journal of the Chemical Society, Chemical Communications, (24), 1993, pp. 1868-1869
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
24
Year of publication
1993
Pages
1868 - 1869
Database
ISI
SICI code
0022-4936(1993):24<1868:SCOAPM>2.0.ZU;2-9
Abstract
The dinuclear complex ion transmer-[(PPri3)2(CO)3Mo(mu-PZ)MO(CO)3(PPri 3)2]+ (pz = pyrazine), the closest yet reported organometallic analogu e of the Creutz-Taube ion [(NH3)5Ru(mu-pz)Ru(NH3)5]5+, has been charac terized as a fully delocalized Mo0.5/Mo0.5 system by electrochemistry, EPR, electronic and vibrational absorption spectroscopy.