Surface photovoltage spectroscopy (SPS) has been employed to monitor o
ptical transitions in quantum well and superlattice structures at room
temperature. Excellent agreement is found between theoretical predict
ions of heavy hole and electron energy level positions and the observe
d transitions. The results show that using this technique, the complet
e band diagram of the quantum structure may be constructed. SPS emerge
s as a powerful tool capable of monitoring optical transitions above t
he lowest one in a simple to interpret, contactless, and nondestructiv
e way. (C) 1996 American Institute of Physics.