We have carried out a transmission electron microscopy based study of
AlGaAs-Al(oxide) heterolayers created by lateral sidewall wet oxidatio
n and identify the oxide phase formed as a consequence of the oxidatio
n of AlAs to be gamma-Al2O3, with the cubic Fd 3m structure. The oxide
-semiconductor interface is weak and porous, possibly due to the high
stress loads developed during oxidation, and we propose that the fast
oxidation rates are a consequence of reactants transported to the oxid
ation front along the porous interface. (C) 1996 American Institute of
Physics.