GLOBAL FITS OF METHYL-METHYL RECOMBINATIONAL DATA TO PREZHDOS NEW INTERPOLATION FORMULA

Authors
HESSLER JP
Citation
Jp. Hessler, GLOBAL FITS OF METHYL-METHYL RECOMBINATIONAL DATA TO PREZHDOS NEW INTERPOLATION FORMULA, Journal of physical chemistry, 100(6), 1996, pp. 2141-2144
Citations number
10
Categorie Soggetti
Chemistry Physical
Journal title
Journal of physical chemistry → ACNP
ISSN journal
00223654
Volume
100
Issue
6
Year of publication
1996
Pages
2141 - 2144
Database
ISI
SICI code
0022-3654(1996)100:6<2141:GFOMRD>2.0.ZU;2-2
Abstract
Prezhdo has suggested (J. Phys. Chem. 1995, 99, 8633) a new interpolat ion formula for the pressure-dependent behavior of dissociative and re combinational reactions. This formula, k(P-r) = k(infinity)[P-p/{1 + P -r + (P-r/B)(A)}], introduces two phenomenological parameters, A and B . Fits to isothermal methyl-methyl recombinational data are used to de termine their temperature dependence. Global fits to an extensive set of data give high-pressure rates coefficients which are compared to va lues derived by other formulations.