Jp. Hessler, GLOBAL FITS OF METHYL-METHYL RECOMBINATIONAL DATA TO PREZHDOS NEW INTERPOLATION FORMULA, Journal of physical chemistry, 100(6), 1996, pp. 2141-2144
Prezhdo has suggested (J. Phys. Chem. 1995, 99, 8633) a new interpolat
ion formula for the pressure-dependent behavior of dissociative and re
combinational reactions. This formula, k(P-r) = k(infinity)[P-p/{1 + P
-r + (P-r/B)(A)}], introduces two phenomenological parameters, A and B
. Fits to isothermal methyl-methyl recombinational data are used to de
termine their temperature dependence. Global fits to an extensive set
of data give high-pressure rates coefficients which are compared to va
lues derived by other formulations.