LOW-FREQUENCY ELECTRICAL-CURRENT OSCILLATIONS IN VAPOR-ADSORBED FERROCENE

Citation
B. Mallik et Ak. Chakraborty, LOW-FREQUENCY ELECTRICAL-CURRENT OSCILLATIONS IN VAPOR-ADSORBED FERROCENE, Journal of physical chemistry, 100(6), 1996, pp. 2145-2147
Citations number
17
Categorie Soggetti
Chemistry Physical
ISSN journal
00223654
Volume
100
Issue
6
Year of publication
1996
Pages
2145 - 2147
Database
ISI
SICI code
0022-3654(1996)100:6<2145:LEOIVF>2.0.ZU;2-Z
Abstract
Systematic low-frequency current oscillations were observed in a parti cular temperature range in the ferrocene sample with adsorbed ethanol vapor in a sandwich type of cell configuration. The frequency of curre nt oscillations was found to decrease with the increasing bias voltage . Experiments with 2-propanol vapor have also been performed. Existing theories of current oscillations in semiconductors have failed to exp lain the observed low-frequency current oscillations in this organomet allic semiconductor. Such current oscillations are possibly associated with some kind of time dependent phase changes in the ferrocene-ethan ol (2-propanol) system/surface layer.