B. Mallik et Ak. Chakraborty, LOW-FREQUENCY ELECTRICAL-CURRENT OSCILLATIONS IN VAPOR-ADSORBED FERROCENE, Journal of physical chemistry, 100(6), 1996, pp. 2145-2147
Systematic low-frequency current oscillations were observed in a parti
cular temperature range in the ferrocene sample with adsorbed ethanol
vapor in a sandwich type of cell configuration. The frequency of curre
nt oscillations was found to decrease with the increasing bias voltage
. Experiments with 2-propanol vapor have also been performed. Existing
theories of current oscillations in semiconductors have failed to exp
lain the observed low-frequency current oscillations in this organomet
allic semiconductor. Such current oscillations are possibly associated
with some kind of time dependent phase changes in the ferrocene-ethan
ol (2-propanol) system/surface layer.