The deposition of 1-3 monolayers of Ni or Ag on benzene adsorbed on a
W(110) surface at 90 K was studied by XPS, Auger, work function, UPS,
and thermal desorption measurements. It was found that Ni penetrates b
enzene multilayers to some extent but shows some vestiges of ordered g
rowth underneath benzene. Ag penetrates more than Ni and does not grow
layer by layer-but forms clusters. It is hypothesized that the differ
ences between Ni and Ag arise from the much weaker interaction of Ag w
ith benzene.