T. Sekine et al., MAGNETIC-BEHAVIOR OF THE LAYERED PEROVSKITE FERROMAGNET (P-CYANOANILINIUM(- UNDER HYDROSTATIC-PRESSURE())(2)CUCL42), Chemical physics letters, 249(3-4), 1996, pp. 201-204
The magnetic properties of the layered perovskite ferromagnet (p-cyano
anilinium(+))(2)CuCl42- have been studied under hydrostatic pressures
up to 1 GPa. The ferromagnetic exchange gradually increases with incre
asing pressure and becomes 1.4 times as large at 1 GPa. The pressure d
ependence of the exchange constant can be semiquantitatively interpret
ed in terms of the shrinkage of the Cu-Cl-Cu superexchange pathway.