ADSORPTION OF NEOPENTANE ON HNAY-FAU ZEOLITE STUDIED BY IR SPECTROSCOPY

Authors
KIRICSI I TASI G FORSTER H FEJES P
Citation
I. Kiricsi et al., ADSORPTION OF NEOPENTANE ON HNAY-FAU ZEOLITE STUDIED BY IR SPECTROSCOPY, Journal of molecular structure, 317(1-2), 1994, pp. 33-37
Citations number
16
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular structure → ACNP
ISSN journal
00222860
Volume
317
Issue
1-2
Year of publication
1994
Pages
33 - 37
Database
ISI
SICI code
0022-2860(1994)317:1-2<33:AONOHZ>2.0.ZU;2-T
Abstract
Adsorption of neopentane on HNaY-FAU zeolite was studied by IR spectro scopy. At beam temperature neopentane already shows a weak interaction with Bronsted acidic sites. At high temperatures, irreversible consum ption of both Bronsted and Lewis sites is observed. According to the r esults of quantum chemical calculations a proton attack on the central carbon of neopentane seems to be favoured.