IRON SUBSTITUTION IN SOIL AND SYNTHETIC ANATASE

Iron(III) for Ti-IV substitution in the structure of pedogenic and syn thetic anatase of up to Fe/(Ti+Fe) 0.1 mol/mol was indicated by an inc rease in unit cell size as measured by XRD line shifts. Mossbauer- and electron paramagnetic resonance spectra at both, 298 K and 4.2 K supp orted this by the presence of signals typical for octahedrally coordin ated Fem in a diamagnetic matrix. Charge compensation was achieved by structural OH, as indicated by FTIR bands at 3360 and 960 cm(-1), whic h were absent in pure anatase and which disappeared on heating. The we ight loss on heating amounted to ca. 0.5 mol H2O/mol Fe. At 600 degree s C structural Fe was ejected, the unit cell size decreased to that of pure anatase, and pseudobrookite, Fe2TiO5, was formed.