O. Kanert et al., SIGNIFICANT DIFFERENCES BETWEEN NUCLEAR-SPIN RELAXATION AND CONDUCTIVITY RELAXATION IN LOW-CONDUCTIVITY GLASSES, Physical review. B, Condensed matter, 49(1), 1994, pp. 76-82
A unified model of ionic motion in glasses is presented which relates
consistently the different quantities observed in nuclear-spin relaxat
ion and electrical-conductivity relaxation due to thermally activated
ionic diffusion. Corresponding experimental data obtained in a low-ion
ic-conductivity fluorozirconate glass are shown to be in reasonable ag
reement with the resent approach. Limitations of the model are pointed
out and are discussed in view of observed deviations between the diff
erent experimental results.