Spin resolved (e,2e) experiments provide an extremely sensitive test o
f theories of electron impact ionization and many-body Coulomb effects
. We present here results for (e,2e) collisions with xenon which show
the First experimental evidence of the fine structure effect in electr
on impact ionization, analogous to the well known effect in electron i
mpact excitation of atoms by polarized electrons. Comparison with dist
orted-wave Born-approximation calculations shows the sensitivity of th
e results to details of the target atom wave functions as well as the
treatment of relativistic effects.