Polarization of the cosmic microwave background, though not yet detect
ed, provides a source of information about cosmological parameters com
plementary to temperature fluctuations. This paper provides a complete
theoretical treatment of polarization fluctuations. After a discussio
n of the physics of polarization, the Boltzmann equation governing the
evolution of the photon density matrix is derived from quantum theory
and applied to microwave background fluctuations, resulting in a comp
lete set of transport equations for the Stokes parameters from both sc
alar and tensor metric perturbations. This approach is equivalent at l
owest order in scattering kinematics to classical radiative transfer,
and provides a general framework for treating the cosmological evoluti
on of density matrices. The metric perturbations are treated in the ph
ysically appealing longitudinal gauge. Expressions for various tempera
ture and polarization correlation functions are derived. Detection pro
spects and theoretical utility of microwave background polarization ar
e briefly discussed. (C) 1996 Academic Press, Inc.