In this paper we present measurements of the thermal diffusivities of
five glasses between 100 and 500 K. These glasses have composition 0.1
5(Na2O)0.15(MO)0.05(Eu2O3)0.65(SiO2), where M is a divalent network mo
difier Mg, Ca, Sr, Ba, or Zn. The thermal transport is represented by
a two-carrier model of conventional phonon-gas transport by extended p
honons and thermally activated hopping of phonons whose eigenvectors a
re localized in the disordered network of the glass. The later contrib
ution is required to explain the increase in the thermal diffusivity a
t temperatures above room temperature. The extended phonons produce a
transport that is a decreasing function of temperature between 100 and
250 K in these glasses. Using the boson peak from Raman scattering as
a measure of the phonon mobility edge, agreement with the temperature
and frequency dependence. of the two-localized-one-extended-phonon an
harmonic process studied by Jagannathan et al. is obtained for both th
e localized and the extended phonons. The model is also applied to fus
ed silica to account for results between 100 and 1100 K, with the modi
fication that the limiting process for the extended states does not ex
plicitly depend on temperature.