P. Calvani et al., POLARONIC OPTICAL-ABSORPTION IN ELECTRON-DOPED AND HOLE-DOPED CUPRATES, Physical review. B, Condensed matter, 53(5), 1996, pp. 2756-2766
Polaronic features similar to those previously observed in the photoin
duced spectra of cuprates have been detected in the reflectivity spect
ra of chemically doped parent compounds of high-critical-temperature s
uperconductors, both n type and p type. In Nd2CuO4-y these features, w
hose intensities depend both on doping and temperature, include local
vibrational modes in the far infrared and a broad band centered at sim
ilar to 1000 cm(-1). The latter band is produced by the overtones of t
wo (or three) local modes and is well described in terms of a small-po
laron model, with a binding energy of about 500 cm(-1). Most of the ab
ove infrared features are shown to survive in the metallic phase of Nd
2-xCexCuO4-y, Bi2Sr2CuO6, and YBa2Cu3O7-y, where they appear as extra-
Drude peaks. The occurrence of polarons is attributed to local modes s
trongly coupled to carriers, as shown by a comparison with tunneling r
esults.