TRIFLUOROACETONYL RADICALS - A VERSATILE APPROACH TO TRIFLUOROMETHYL KETONES

Citation
Mp. Denieul et al., TRIFLUOROACETONYL RADICALS - A VERSATILE APPROACH TO TRIFLUOROMETHYL KETONES, Chemical communications, (22), 1996, pp. 2511-2512
Citations number
26
Categorie Soggetti
Chemistry
Journal title
ISSN journal
13597345
Issue
22
Year of publication
1996
Pages
2511 - 2512
Database
ISI
SICI code
1359-7345(1996):22<2511:TR-AVA>2.0.ZU;2-Z
Abstract
Radical addition of S-trifluoroacetonyl O-neopentyl dithiocarbonate Ic across an alkene occurs smoothly in the presence of a small amount of dilauroyl peroxide as initiator to give variously functionalised trif luoromethyl ketones in good yields.