AGGREGATION OF TRIPODAL THALLIUM(I) AMIDES THROUGH WEAK TL-I-CENTER-DOT-CENTER-DOT-CENTER-DOT-TL-I INTERACTIONS

Authors
HELLMANN KW GADE LH SCOWEN IJ MCPARTLIN M
Citation
Kw. Hellmann et al., AGGREGATION OF TRIPODAL THALLIUM(I) AMIDES THROUGH WEAK TL-I-CENTER-DOT-CENTER-DOT-CENTER-DOT-TL-I INTERACTIONS, Chemical communications, (22), 1996, pp. 2515-2516
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
22
Year of publication
1996
Pages
2515 - 2516
Database
ISI
SICI code
1359-7345(1996):22<2515:AOTTAT>2.0.ZU;2-A
Abstract
Metal exchange between the lithium amide MeSi[SiMe(2)N-(Li)Bu(t)](3) a nd TICl yields the corresponding thallium amide MeSi[SiMe(2)N(Tl)Bu(t) ](3) 1 which aggregates in the solid through weak attractive TI TI int eractions to form infinite molecular chains; competing redox chemistry leads to the dimetallated species HC[SiMe(2)N(Tl)Bu(t)](2)[SiMe(2)NHB u(t)] 2 in the analogous metal-exchange process involving the trisilyl methane derivative.