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Detailed multinuclear magnetic resonance studies on phenylphosphonic d
ichloride oriented in mixed and individual nematic liquid crystals hav
e been carried out. Analysis of the H-1, C-13, and P-31 NMR spectra pr
ovided precise geometrical and orientational parameters and the signs
and the magnitudes of the indirect spin-spin couplings between heteron
uclei. (C) 1996 Academic Press, Inc.