EXO SELECTIVE DIELS-ALDER REACTION OF NITROOLEFINS WITH DANISHEFSKYS DIENE

Authors
NODE M NISHIDE K IMAZATO H KUROSAKI R INOUE T IKARIYA T
Citation
M. Node et al., EXO SELECTIVE DIELS-ALDER REACTION OF NITROOLEFINS WITH DANISHEFSKYS DIENE, Chemical communications, (22), 1996, pp. 2559-2560
Citations number
25
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
22
Year of publication
1996
Pages
2559 - 2560
Database
ISI
SICI code
1359-7345(1996):22<2559:ESDRON>2.0.ZU;2-4
Abstract
Diels-Alder reaction of nitroolefins with Danishefsky's diene exhibit abnormal exo selectivity based on electrostatic repulsion between the nitro group and the silyloxy group of diene.