REACTIONS OF CARBONYL-COMPOUNDS IN BASIC SOLUTIONS .19. ALKALINE-HYDROLYSIS OF METHYL 2'-FORMYLBIPHENYL-2-CARBOXYLATE

Authors
BOWDEN K MANNING CS
Citation
K. Bowden et Cs. Manning, REACTIONS OF CARBONYL-COMPOUNDS IN BASIC SOLUTIONS .19. ALKALINE-HYDROLYSIS OF METHYL 2'-FORMYLBIPHENYL-2-CARBOXYLATE, Journal of chemical research. Synopses, (1), 1994, pp. 28-29
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
1
Year of publication
1994
Pages
28 - 29
Database
ISI
SICI code
0308-2342(1994):1<28:ROCIBS>2.0.ZU;2-7
Abstract
Rate coefficients have been measured for the alkaline hydrolysis of me thyl 2'-formylbiphenyl-2-carboxylate in 70% (v/v) dioxane-water at sev eral temperatures; the relative rate of hydrolysis and the activation parameters indicate the occurrence of neighbouring group participation by the formyl group in alkaline hydrolysis, there being no evidence f or significant ring-chain tautomerism in the 2'-formyl acid from ionis ation and spectral measurements.