FIRST DICOPPER(II) COMPLEX TO CONTAIN BRIDGING MACROCYCLIC PYRIDAZINEUNITS - STRUCTURE, ELECTROCHEMISTRY AND MAGNETOCHEMISTRY OF [CU(2)L(MECN)(2)(CLO4)(2)][CLO4](2)

Authors
BROOKER S KELLY RK MOUBARAKI B MURRAY KS
Citation
S. Brooker et al., FIRST DICOPPER(II) COMPLEX TO CONTAIN BRIDGING MACROCYCLIC PYRIDAZINEUNITS - STRUCTURE, ELECTROCHEMISTRY AND MAGNETOCHEMISTRY OF [CU(2)L(MECN)(2)(CLO4)(2)][CLO4](2), Chemical communications, (22), 1996, pp. 2579-2580
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
22
Year of publication
1996
Pages
2579 - 2580
Database
ISI
SICI code
1359-7345(1996):22<2579:FDCTCB>2.0.ZU;2-B
Abstract
Magnetic and electrochemical studies of the structurally characterised dicopper(n) complex [Cu(2)L(MeCN)(2)(ClO4)(2)][ClO4](2) 1, the first to be bridged by two pyridazine units held within a (2 + 2) macrocycli c ligand, reveal strong antiferromagnetic exchange as well as two well separated reversible one-electron reductions at positive potentials.