AN EPR STUDY ON THE BINDING OF OXOVANADIUM(IV) TO NUCLEOSIDE MONOPHOSPHATES - EVIDENCE FOR THE INVOLVEMENT OF THE PURINE MOIETY IN THE COMPLEXES OF ADENOSINE 5'-MONOPHOSPHATE
E. Alberico et al., AN EPR STUDY ON THE BINDING OF OXOVANADIUM(IV) TO NUCLEOSIDE MONOPHOSPHATES - EVIDENCE FOR THE INVOLVEMENT OF THE PURINE MOIETY IN THE COMPLEXES OF ADENOSINE 5'-MONOPHOSPHATE, Journal of chemical research. Synopses, (1), 1994, pp. 42-43
Binding of oxovanadium(IV) to ribonucleoside monophosphates, which inv
olves initially the formation of VO(IV)-phosphate bonds and then the t
ransfer of the metal ion to the deprotonated pair of 2',3'-hydroxy gro
ups, may also yield species which are stabilised by interaction of oxo
vanadium(IV) with phosphate and the N(7) atom of the adenine moiety.