O-H ... PI(ARENE) INTERMOLECULAR HYDROGEN-BONDING IN THE STRUCTURE OF1,1,2-TRIPHENYLETHANOL

Citation
G. Ferguson et al., O-H ... PI(ARENE) INTERMOLECULAR HYDROGEN-BONDING IN THE STRUCTURE OF1,1,2-TRIPHENYLETHANOL, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 70-73
Citations number
20
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
1
Pages
70 - 73
Database
ISI
SICI code
0108-2701(1994)50:<70:O.PIHI>2.0.ZU;2-P
Abstract
The 1,1,2-triphenylethanol molecule, Ph2(PhCH2)COH (1), forms centrosy mmetric dimers in the solid state. The shortest O ... O separation, 5. 837 (3) angstrom, is too long for any O-H ... O hydrogen-bond formatio n. Instead, there are O-H ... pi(arene) interactions between the hydro xyl group of one molecule and a phenyl group of a centrosymmetrically related molecule. The O ... C and H ... C distances between the hydrox yl group and the closest phenyl-ring C atom are 3.525 (4) and 2.73 (4) angstrom, respectively. These intermolecular contacts are the only dr iving force towards dimer formation in the solid state.