G. Ferguson et al., O-H ... PI(ARENE) INTERMOLECULAR HYDROGEN-BONDING IN THE STRUCTURE OF1,1,2-TRIPHENYLETHANOL, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 70-73
The 1,1,2-triphenylethanol molecule, Ph2(PhCH2)COH (1), forms centrosy
mmetric dimers in the solid state. The shortest O ... O separation, 5.
837 (3) angstrom, is too long for any O-H ... O hydrogen-bond formatio
n. Instead, there are O-H ... pi(arene) interactions between the hydro
xyl group of one molecule and a phenyl group of a centrosymmetrically
related molecule. The O ... C and H ... C distances between the hydrox
yl group and the closest phenyl-ring C atom are 3.525 (4) and 2.73 (4)
angstrom, respectively. These intermolecular contacts are the only dr
iving force towards dimer formation in the solid state.