The structural characteristics of GaN films grown on sapphire substrat
es by molecular beam epitaxy have been investigated using high-resolut
ion synchrotron x-ray diffraction and electron microscopy. We find rem
arkable correspondence between the in-plane structural order (coherenc
e length and mosaic spread) and the electrical and optical properties.
Contrary to common belief, our observations show unequivocally that t
he out-of-plane structural features, which are considerably better dev
eloped than the in-plane counterparts, cannot be used for determining
the material quality with respect to their optical and electrical acti
vity. In particular, the (001) mosaic spread is not a good indicator o
f film quality. (C) 1996 American Institute of Physics.