By means of transmission Mossbauer spectroscopy, the effect of mechani
cal milling on the magnetic anisotropy of Fe80B20 metallic glass has b
een studied. On the basis of variation of the areal ratio R(21) of the
second to the first Mossbauer line with milling time, it was found th
at a rotation of the average magnetic-moment directions from the in-pl
ane to an out-of-plane orientation may take place by mechanical millin
g without onset of bulk crystallization, and that the distribution of
the magnetic-moment directions becomes random after the bulk crystalli
zation has occurred. The induced out-of-plane magnetic anisotropy by m
echanical milling can be attributed to the occurrence of the chemical
short-range order and surface crystallization in the Fe80B20 metallic
glass. The latter effect may cause the formation of compressive stress
es in the bulk and therefore a rotation of magnetic-moment directions
in the Fe80B20 metallic glass. (C) 1996 American Institute of Physics.