AN ISOPERIBOL DROP CALORIMETER

Authors
BLACHNIK R BESSER J WALLBRECHT P DREYER K
Citation
R. Blachnik et al., AN ISOPERIBOL DROP CALORIMETER, Thermochimica acta, 271, 1996, pp. 85-92
Citations number
7
Categorie Soggetti
Chemistry Analytical
Journal title
Thermochimica acta → ACNP
ISSN journal
00406031
Volume
271
Year of publication
1996
Pages
85 - 92
Database
ISI
SICI code
0040-6031(1996)271:<85:AIDC>2.0.ZU;2-F
Abstract
An isoperibol calorimeter is described. Its operation involves the dro p of a sample from temperatures up to 1373 K into a metal block at 298 .15 K. By this method the enthalpy contents of the samples can be meas ured. The calibration factor, obtained by electrical and drop calibrat ions, had a reproducibility of +/-0.11%. The calorimeter was tested by determining the enthalpy of silver; agreement with the data of Barin was within a range of +1%.