4 DIFFERENT COORDINATION POLYHEDRA AROUND COPPER IN THE OXIDE-ARSENATE-PHOSPHATE CUO(CU,MG)(3)(AS1-XPXO4)(2) (X=0.3)

Authors
FRERICHS D MULLERBUSCHBAUM H
Citation
D. Frerichs et H. Mullerbuschbaum, 4 DIFFERENT COORDINATION POLYHEDRA AROUND COPPER IN THE OXIDE-ARSENATE-PHOSPHATE CUO(CU,MG)(3)(AS1-XPXO4)(2) (X=0.3), Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 51(1), 1996, pp. 25-28
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
51
Issue
1
Year of publication
1996
Pages
25 - 28
Database
ISI
SICI code
0932-0776(1996)51:1<25:4DCPAC>2.0.ZU;2-D
Abstract
Single crystals of CuO(Cu,Mg)(3) [(AS(0.7)P(0.3))O-4](2) have been pre pared by crystallization from melts. The compound crystallizes with tr iclinic symmetry, space group C-i(1)-<P(1)over bar>, a = 6.372(4), b = 7.643(7), c = 8.175(5) Angstrom, alpha = 98.59(6), beta = 112.26(3), gamma = 99.03(3)degrees, Z = 2. CuO(Cu,Mg)(3)[(As0,7P0,3)O-4](2) is is otypic to CU4(PO4)(2)O. X-ray investigations show square planar CuO4 p olygons, twisted tetragonal CuO5 pyramids, CuO5 bipyramids and elongat ed (Cu,Mg)O-6 octahedra.