E. Peters et H. Mullerbuschbaum, ON A LOW-VALENT TITANIUM TUNGSTEN-OXIDE - TI0.54W0.46O2, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 51(1), 1996, pp. 29-31
Single crystals of Ti0.54W0.O-46(2) have been prepared by CO2-LASER te
chniques. This phase crystallizes with a non-distorted rutile structur
e, space group D-4h(14)-P4(2)/mnm, a = 4.6862(4), c = 2.9039(3) Angstr
om, Z = 2. Split positions of the statistically distributed metal ions
show the existence of W-W pair formation as reported for pure WO2.