MOLECULAR WIRES - AN ELECTROCHEMICAL STUDY OF METAL-METAL INTERACTIONS THROUGH CHAINS OF 4 CARBON-ATOMS

Authors
THOMAS JA JONES CJ MCCLEVERTY JA HUTCHINGS MG
Citation
Ja. Thomas et al., MOLECULAR WIRES - AN ELECTROCHEMICAL STUDY OF METAL-METAL INTERACTIONS THROUGH CHAINS OF 4 CARBON-ATOMS, Polyhedron, 15(9), 1996, pp. 1409-1414
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
9
Year of publication
1996
Pages
1409 - 1414
Database
ISI
SICI code
0277-5387(1996)15:9<1409:MW-AES>2.0.ZU;2-B
Abstract
The new complexes [Mo(Tp)(NO)Cl(O-Z-OH)] {Tp* = HB(3,5-Me(2)C(3)HN(2) )(3); Z = -CH2CH2CH2CH2-, -CH2CH=CHCH2- and -CH2 drop CCH2-} and [{Mo (Tp)(NO)Cl}(2)(O-Z-O)] have been synthesized and characterized. Elect rochemical studies reveal respective comproportionation constants of 5 0, 349 and 108 for the bimetallic complexes with the alkene bridge giv ing the largest metal-metal interaction and the alkane the smallest.