SYNTHESIS AND PROPERTIES OF THE COMPLEXES OF LANTHANIDES WITH NITRONYL NITROXIDES

Authors
JIANG ZH ZHANG W LIAO DZ HUAN ZW QI YQ WANG GL
Citation
Zh. Jiang et al., SYNTHESIS AND PROPERTIES OF THE COMPLEXES OF LANTHANIDES WITH NITRONYL NITROXIDES, Polyhedron, 15(9), 1996, pp. 1429-1431
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
9
Year of publication
1996
Pages
1429 - 1431
Database
ISI
SICI code
0277-5387(1996)15:9<1429:SAPOTC>2.0.ZU;2-U
Abstract
Six novel complexes of formula [Ln(pfpr)(3)](3)(NITF)2 . nH(2)O, where Ln = Nd, Gd, Dy, Ho, Er, Y; pfpr = pentafluoropropionate; NITF = ryl- 4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide, and n = 6 (for Nd); 1 ( for Dy); 2 (for Y); 0 (for Gd, Ho and Er), have been synthesized. Thes e complexes were characterized by elemental analysis, IR, electronic s pectra, molar conductances. The variable temperature (4-300 K)magnetic susceptibility of the complex [Gd(pfpr)(3)](3)(NITF) was determined.